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heterolytic

heterolytic

1 9.9
A bond that breaks so both electrons go to one atom and make a positive and negative ion
  • adjective
  • /ˌhɛtərəˈlɪtɪk/
  • Specialized
: heterolítico
  • The chemist explained that a heterolytic bond breaking can lead to the formation of two distinct ions.
  • heterolytic O-O bond

Examples

  • In a heterolytic cleavage, the bond breaks so that one atom gains both electrons and becomes negatively charged.

  • From these complexes, the reaction may proceed via the two different mechanisms (homolytic and heterolytic) presented in Schemes 5 and 6, respectively.

    Academic text (2001)
  • During the reaction, the heterolytic dissociation resulted in one atom carrying both electrons from the broken bond.

Antonyms

homolytic
  • Specialized
1 9.9

A bond that breaks so each atom keeps one electron, making two atoms with one unpaired electron

Surface Forms

heterolytic positive

Morphology

heterolytic = lytic (semi-transparent) = hetero + lytic

The adjective is formed by regular prefixation of 'hetero-' to the adjective 'lytic'; the morphological operation is predictable even if the content is technical.

Etymology

Heterolytic comes from the parts hetero- meaning 'different' and -lytic meaning 'to break', the same -lytic you see in electrolysis. So a heterolytic break is an uneven break where both electrons go to one atom, making 'ions' or charged atoms, which is why the word is used for reactions that produce ions.